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What is Fajan's rule?

Updated: 4/28/2022
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12y ago

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Fajans' Rules, formulated by Kazimierz Fajans in 1923, are used to predict whether a chemical bond will be covalentor ionic, and depend on the charge on the cation and the relative sizes of the cation and anion.

IonicCovalentLow positive chargeHigh positive chargeLarge cationSmall cationSmall anionLarge anion

Thus sodium chloride (with a low positive charge (+1), a fairly large cation (~1 Å) and relatively small anion (2Å) is ionic; but aluminum iodide (AlI3) (with a high positive charge (+3) and a large anion) is covalent.

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Maksymilian Fajans died in 1890.


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Maksymilian Fajans was born in 1827.


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