Fajans' Rules, formulated by Kazimierz Fajans in 1923, are used to predict whether a chemical bond will be covalentor ionic, and depend on the charge on the cation and the relative sizes of the cation and anion.
IonicCovalentLow positive chargeHigh positive chargeLarge cationSmall cationSmall anionLarge anion
Thus sodium chloride (with a low positive charge (+1), a fairly large cation (~1 Å) and relatively small anion (2Å) is ionic; but aluminum iodide (AlI3) (with a high positive charge (+3) and a large anion) is covalent.
Protactinium was discovered in 1913 by Fajans and Gohring in Karlsruhe, Germany.
LiI. Iodine is less electronegative. Li is very polarising and I- is more readily polarised (fajans rules)
Ionic. BUT because of Fajans rules silver salts have significant covalent character which expalins the low solubility of silver chloride.
No. But Li+ is small and polarising (Fajans rules apply)- so the salt is a little different in its behaviour from the other group 1 chlorides.
Smaller higher charged cations are more polarising and this gives more covalent character. Larger cations are conversely less polarising. This is "Fajans Rules"
Maksymilian Fajans died in 1890.
Maksymilian Fajans was born in 1827.
Kazimierz Fajans died on 1975-05-18.
Kazimierz Fajans was born on 1887-05-27.
K. Fajans has written: 'A textbook of practical physical chemistry'
Michael Fajans has written: 'An alternative to the automobile' -- subject(s): Berkeley University of California, Choice of transportation, Students, Transportation
No. Fajans method relies on the naked eye, which is not as precise as analytical instruments.
Protactinium was discovered in 1913 by Fajans and Gohring in Karlsruhe, Germany.
Protactinium was discovered in 1913 by Fajans and Gohring in Karlsruhe, Germany.
LiI. Iodine is less electronegative. Li is very polarising and I- is more readily polarised (fajans rules)
Ionic. BUT because of Fajans rules silver salts have significant covalent character which expalins the low solubility of silver chloride.
No. But Li+ is small and polarising (Fajans rules apply)- so the salt is a little different in its behaviour from the other group 1 chlorides.