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Hydrogen BondsIn a compound, there may be atoms with different levels of attraction to electrons. This attraction is called "electronegativity." If one atom in a compound "likes" electrons more (and has a higher electronegativity), the electrons shared between the molecules will spend more time on the atom with a higher electronegativity. Because electrons are negative, the atom that has a stronger attraction will be slightly negative (δ−) while the other atoms will be slightly positive (δ+). In all compounds that have hydrogen bonds, the hydrogen atom(s) is/are the positive atom and the other atom (usually nitrogen, fluorine, or oxygen) is the electronegative negative one.

This slight polarity on the molecule allows it to interact with other molecules of similar charge. The negative atom of one molecule (like nitrogen, fluorine, or oxygen) will bind to the positive hydrogen in another molecule. The bond between the two is a hydrogen bond. It is not a strong bond like a covalent, nor does it actually involve the transfer of electrons, but it does cause two molecules to "stick" together.

The classic (and the most important) case of hydrogen bonding is with water. There are a number of emergent properties of water that are due to the hydrogen bonds, one of which is floating ice. To see an explanation of the hydrogen bonds at work that cause ice to float, see the related question in the "Related Questions" section below.

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14y ago

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