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S, P, D, and F are the letters assigned to the four different orbital shapes. An orbital is the area around the nucleus of an atom where you find electrons. Not all atoms have the four shapes though; the most basic elements (Hydrogen, with one electron for example) start with the S shape only, and add more shapes, as they become more complex, adding in order of S, P, D, and finally F. Each orbital has a limit to how many electrons it can hold: S can only hold 2 electrons, P holds 6, D holds 10, and F holds 14. The S orbital is spherical, P looks something like a peanut, and D like a doughnut. The F orbital is very complex, rarely used, and only found in elements with very high atomic numbers.

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