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Chromium reacts directly with fluorine, F2, at 400°C and 200-300 atmospheres to form chromium(VI) fluoride, CrF6.

Cr(s) + 3F2(g) → CrF6(s) [yellow]

Under milder conditions, chromium(V) fluoride, CrF5, is formed.

2Cr(s) + 5F2(g) → 2CrF5(s) [red]

Under still milder conditions, chromium metal reacts with the halogens fluorine, F2, chlorine, Cl2, bromine, Br2, and iodine, I2, to form the corresponding trihalides chromium(III) fluoride, CrF3, chromium(III) chloride, CrCl3, chromium(III) bromide, CrBr3, or chromium(III) iodide, CrI3.

2Cr(s) + 3F2(g) → 2CrF3(s) [green]

2Cr(s) + 3Cl2(g) → 2CrCl3(s) [red-violet]

2Cr(s) + 3Br2(g) → 2CrBr3(s) [very dark green]

2Cr(s) + 3I2(g) → 2CrI3(s) [very dark green]

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