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The mass of a substance, according to Faraday's law, produced or consumed by electrolysiswith 100% current efficiency during the flow of a quantity of electricity equal to 1 faradayor 96,487 coulomb(1 coulomb corresponds to a current of 1 ampere during 1 second). Electrochemical equivalents are essential in the calculation of the current efficiency of an electrodeprocess.

The electrochemical equivalent of a substance is equal to the gram-atomic or gram-molecular mass of this substance divided by the number of electrons involved in the electrode reaction. For example, the electrochemical-2equivalent of zinc, for which two electrons are required in order to deposit one atom, is Zn/2 or 65.37/2 g. Thus, the faraday is equal to the product of the charge of the electron times the number of electrons (the avogadro-s-number) required to react with 1 atom- or molecule-equivalent of substance. See also Coulometer.

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