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The outer electrons of As is 5, and there are 3 bonded Cl's. this makes the * electrons for the octet rule to be obeyed. therefore AsCl3 will bond with one lone pair, thus the bond angle will deviate from the ideal tetrahedral angle of 109.50.

VSEPR theory predicts that lone-pair bonding pair repusions are stronger than bondonding pair- bonding pair repulsions and the bond angle is predicted to be less than 109.50. the actual bond angle is around 980

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