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The name phosphite is according to IUPAC reserved for PO33- ion, so Cesium phosphite would be Cs3PO3

However no compounds containing PO33- are known to exist. Hypothetical compounds containing it are often used in naming exercises by teachers/colleges/web sites. Phosphite in common use refers to HPO32- ion (IUPAC name phosphonate) and this is the formula taught in some parts of the world, cesium phosphite would therefore be Cs2HPO3

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