the melting/ freezing point is approximately 50°C
sodium chloride melt earlier because it has low freezing point
The melting point of a mixture of 50% 2-naphthol and 50% benzoic acid will depend on the exact proportion of each compound present and any potential interactions between them. However, the melting points of the individual compounds are approximately 122°C for 2-naphthol and 122-123°C for benzoic acid.
The eutectic temperature for the benzoic and mandelic acid system is approximately 119°C. At this temperature, both compounds will fully dissolve in each other to form a eutectic mixture, exhibiting the lowest melting point in the system.
The literature value of the melting point of pure benzoic acid is about 122.4 degrees Celsius, while the literature value of the melting point of pure 2-naphthol is close at 122 degrees Celsius. Nevertheless, the melting point of the benzoic acid should be depressed (go down) compared to the literature value if you were to add 2-naphthol because the sample you were testing would then be impure, even if that impurity does have a similar melting point. Also, the range over which the sample melts should get larger as well. Instead of melting within a degree or less, it may melt over the course of several degrees. So I just tested this in lab, and I can't promise that this is 50/50, but my melting point for 2-naphthol with Benzoic acid is 104.1-106.0 degrees Celsius This is a very basic answer, and the trend is true. However, with my organic chemistry professor, this answer would be followed by a blank look and "Why?" The best way to think of this is to look at the chemical structure of Benzoic Acid and 2-naphthol separate. Go ahead and Google it on a new tab. Now look at the molecule of the two together. And think: "What does the composite molecule have that the two alone don't?" Give up? Electronegativity. The more electronegative a molecule is the greater its reactivity. As in the compound molecule will melt easier than the two 'pure' substances.
One way to separate benzoic acid from a mixture of naphthalene and benzoic acid is by sublimation. Naphthalene sublimes at a lower temperature compared to benzoic acid, allowing for the separation of the two compounds based on their difference in sublimation temperatures. By heating the mixture and collecting the sublimate, one can isolate benzoic acid from naphthalene.
sodium chloride melt earlier because it has low freezing point
Benzoic acid has a high melting point because it forms strong intermolecular hydrogen bonds between its molecules. These bonds require a lot of energy to break, resulting in a high melting point. Additionally, benzoic acid molecules are relatively large and exhibit a high degree of symmetry, contributing to its strong intermolecular forces.
Benzoic Acid has a melting point of 122oC. If your sample did not melt even at 200oC, then you can only assume that the sample in Whole or Part was not Benzoic Acid. It must have been contaminated with some other compound with a much higher melting point.
The student's approach to isolating and testing the purity of benzoic acid is appropriate, as recrystallization is a common method for purifying solids. After scraping the dried benzoic acid from the filter paper, taking the melting point is a valid method for assessing purity; pure substances have a sharp melting point range, while impurities typically depress and broaden this range. If the observed melting point of the recrystallized benzoic acid closely matches the literature value for pure benzoic acid, it suggests successful purification. Conversely, a significant deviation would indicate the presence of impurities.
One example of an acid with a melting point around 69 degrees Celsius is benzoic acid. It has a melting point of 122-123 degrees Fahrenheit, which is approximately 50-51 degrees Celsius.
Physical properties of benzoic acid:-density: 1,2659 g/cm3-melting point: 122,41 oC-boiling point: 249,2 oC-refractive index: 1,5397
The melting point of a mixture of 50% 2-naphthol and 50% benzoic acid will depend on the exact proportion of each compound present and any potential interactions between them. However, the melting points of the individual compounds are approximately 122°C for 2-naphthol and 122-123°C for benzoic acid.
The eutectic temperature for the benzoic and mandelic acid system is approximately 119°C. At this temperature, both compounds will fully dissolve in each other to form a eutectic mixture, exhibiting the lowest melting point in the system.
The literature value of the melting point of pure benzoic acid is about 122.4 degrees Celsius, while the literature value of the melting point of pure 2-naphthol is close at 122 degrees Celsius. Nevertheless, the melting point of the benzoic acid should be depressed (go down) compared to the literature value if you were to add 2-naphthol because the sample you were testing would then be impure, even if that impurity does have a similar melting point. Also, the range over which the sample melts should get larger as well. Instead of melting within a degree or less, it may melt over the course of several degrees. So I just tested this in lab, and I can't promise that this is 50/50, but my melting point for 2-naphthol with Benzoic acid is 104.1-106.0 degrees Celsius This is a very basic answer, and the trend is true. However, with my organic chemistry professor, this answer would be followed by a blank look and "Why?" The best way to think of this is to look at the chemical structure of Benzoic Acid and 2-naphthol separate. Go ahead and Google it on a new tab. Now look at the molecule of the two together. And think: "What does the composite molecule have that the two alone don't?" Give up? Electronegativity. The more electronegative a molecule is the greater its reactivity. As in the compound molecule will melt easier than the two 'pure' substances.
A melting point mixture typically consists of a 1:1 ratio of the compound being tested and a known standard compound, such as benzoic acid. The mixture is heated slowly to determine the melting point range of the unknown compound. By comparing the melting point range of the unknown compound to that of the standard, the identity or purity of the unknown compound can be determined.
The acetic acid melting point is approx. 17 oC.
Lets see. Add neutral ferric chloride to the sample solution. A coloured solution is obtained if it is 2-naphthol (most phenols give colour with neutral ferric chloride solution). Add sodium bicarbonate to the sample solution. Carboxylic acids evolve carbon dioxide gas. Phenols (except strong ones like picric acid) does not. Both 2-naphthol and benzoic acid will evolve hydrogen when treated with metallic sodium (test not advisable to do) and NaOH. Phenols form pleasent smelling esters when treated with carboxylic acids where as benzoic acid will be fruity odour with alcohols or phenols. Both benzoic acid and 2-naphthol melts about 1220C whereas the boiling point of benzoic acid is 2490C and that of 2-naphthol is 2850C.