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Alkali Metals (group 1) because they only need to lose one electron in order to have a stable valence level of 8. As you go down the alkali metals group, the elements become more reactive. So Francium is the most reactive alkali metal.

Also, Halogens, because they already have 7 electrons and only need to gain one in order to have a stable valence level of 8. As you go up the halogens group, the elements become more reactive. So Fluorine is the most reactive halogen.

This is just a brief summary, if you want to know the reasons why this is I suggest you search about ionization energy, electron affinity, and electronegativity because these are all what make an element "reactive."

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