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Oxidation number of P in H3PO3 is +3. To calculate the oxidation number

H= 1 except when bonded to metal

O is -2 except when bonded to F

The sum of all of the oxidation number on a molecule /ion is equal to the charge so as H3PO3 is a neutral molecule:-

0 = OxP + 3OxH + 3OxO = Oxp + 3 + (-6)

Oxp = +3

H3PO3 is phosphorus acid. However when you try to make it in aqueous solution, it "tautomerises" , turning into phosphonic acid, HPO(OH)2- same formula H3PO3, but its got a P-H bond and a P=O bond. The oxidation number of P is still 3

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12y ago

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