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The sulfur in potash alum occurs in sulfate ions, which have the formula SO4-2. Since sulfur is less electronegative than oxygen, the oxygen has an oxidation number of -2; 4 atoms of oxygen give a total negative charge of -8, and the sulfur atom must have an oxidation number of +6 to match the -2 charge of the sulfate ion as a whole.

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Q: What is the oxidation number of sulferin potash alum?
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