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You need the atomic masses of P and of F.

P ----> M = 30.97 g/mol

F-----> M = 19.00 g/mol

PF4 ----> M = ( 30.97 ) + ( 4 ) ( 19.00 ) = 106.97 g/mol

mass % P = [ ( 30.97 ) / ( 106.97 ) ] [ 100 ] = 28.95 mass % P<--------

mass % F = [ ( 76.00 ) / ( 106.97 ) ] [ 100 ] = 71.05 mass % F <----------

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Tetrafluorophosphite (PF4-) is an anion not a compound.

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