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There is only one neutral element with 22 electrons: it has also 22 protons in it, so it is atomnumber 22: Titanium.

However with Titanium 22 neutrons (this is the Ti(44)-isotope) can ONLY be made synthetically and is not naturally occurring. It has a halflife of 63 year decaying into Sc(44) by electron capture (e- + p+ -> no )

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