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Since the question seems to be about reactions - and the whole idea of a reaction is that something is changing...

The CHANGE in Gibbs free energy will always be positive for a spontaneous reaction.

As far as whether the Gibbs free energy of a system (without the term "change" attached) ...

Since Gibbs free energy is a state function, it is always defined relative to a standard state. Asking if the Gibbs free energy is positive is akin to asking how "high" something is - the answer depends on where you define zero to be. If you define 0 height to be the level of the ground you are standing on, you will get a different answer than if you define zero height to be "sea level". A cactus in Death Valley may have a positive height relative to the ground, but would actually have a negative height relative to sea level. Likewise, the Gibbs free energy of a system will be positive or negative (or zero) depending on what you define as the standard state.

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Chauncey Kihn

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What is the difference between Gibbs free energy and standard free energy, and how do they relate to each other in chemical reactions?

Gibbs free energy and standard free energy are both measures of the energy available to do work in a chemical reaction. The main difference is that Gibbs free energy takes into account the temperature and pressure of the system, while standard free energy is measured under specific standard conditions. In chemical reactions, the change in Gibbs free energy determines whether a reaction is spontaneous or non-spontaneous. If the Gibbs free energy change is negative, the reaction is spontaneous, while a positive change indicates a non-spontaneous reaction. The relationship between Gibbs free energy and standard free energy lies in the fact that the standard free energy change can be used to calculate the Gibbs free energy change under any conditions.


What is the significance of the Gibbs free energy change (G) in chemical reactions and how does it relate to the spontaneity and equilibrium of a reaction?

The Gibbs free energy change (G) is important in chemical reactions because it indicates whether a reaction is spontaneous or not. If G is negative, the reaction is spontaneous and can proceed without external intervention. If G is positive, the reaction is non-spontaneous and requires external energy input to occur. At equilibrium, G is zero, meaning the forward and reverse reactions are occurring at equal rates.


According to the Gibbs free energy equation G H - TS when is a reaction always spontaneous?

when H is negative and S is positive


What are the units of Gibbs energy and how are they related to the thermodynamic properties of a system?

The units of Gibbs energy are joules (J) or kilojoules (kJ). Gibbs energy is related to the thermodynamic properties of a system by indicating whether a process is spontaneous or non-spontaneous. If the Gibbs energy is negative, the process is spontaneous, and if it is positive, the process is non-spontaneous.


Under what conditions is G for a reaction always positive?

When H is positive and S is negative

Related Questions

What will Gibbs free energy always be positive?

Since the question seems to be about reactions - and the whole idea of a reaction is that something is changing... The CHANGE in Gibbs free energy will always be positive for a spontaneous reaction. As far as whether the Gibbs free energy of a system (without the term "change" attached) ... Since Gibbs free energy is a state function, it is always defined relative to a standard state. Asking if the Gibbs free energy is positive is akin to asking how "high" something is - the answer depends on where you define zero to be. If you define 0 height to be the level of the ground you are standing on, you will get a different answer than if you define zero height to be "sea level". A cactus in Death Valley may have a positive height relative to the ground, but would actually have a negative height relative to sea level. Likewise, the Gibbs free energy of a system will be positive or negative (or zero) depending on what you define as the standard state.


When will Gibbs free energy always be negative?

Gibbs free energy (ΔG) will always be negative for a spontaneous process occurring at constant temperature and pressure. This typically occurs when the change in enthalpy (ΔH) is negative (exothermic reactions) and the change in entropy (ΔS) is positive, leading to a favorable increase in disorder. Additionally, even if ΔH is positive, a sufficiently large positive change in entropy can also result in a negative ΔG at high temperatures, according to the equation ΔG = ΔH - TΔS.


What is the difference between Gibbs free energy and standard free energy, and how do they relate to each other in chemical reactions?

Gibbs free energy and standard free energy are both measures of the energy available to do work in a chemical reaction. The main difference is that Gibbs free energy takes into account the temperature and pressure of the system, while standard free energy is measured under specific standard conditions. In chemical reactions, the change in Gibbs free energy determines whether a reaction is spontaneous or non-spontaneous. If the Gibbs free energy change is negative, the reaction is spontaneous, while a positive change indicates a non-spontaneous reaction. The relationship between Gibbs free energy and standard free energy lies in the fact that the standard free energy change can be used to calculate the Gibbs free energy change under any conditions.


What is the significance of the Gibbs free energy change (G) in chemical reactions and how does it relate to the spontaneity and equilibrium of a reaction?

The Gibbs free energy change (G) is important in chemical reactions because it indicates whether a reaction is spontaneous or not. If G is negative, the reaction is spontaneous and can proceed without external intervention. If G is positive, the reaction is non-spontaneous and requires external energy input to occur. At equilibrium, G is zero, meaning the forward and reverse reactions are occurring at equal rates.


An endergonic reaction is a reaction in which the change in Gibbs free energy is what?

An endergonic reaction is a reaction in which the change in Gibbs free energy is positive, indicating that the reaction requires an input of energy to proceed. This means that the products of the reaction have more free energy than the reactants.


According to the Gibbs free energy equation G H - TS when is a reaction always spontaneous?

when H is negative and S is positive


What are the units of Gibbs energy and how are they related to the thermodynamic properties of a system?

The units of Gibbs energy are joules (J) or kilojoules (kJ). Gibbs energy is related to the thermodynamic properties of a system by indicating whether a process is spontaneous or non-spontaneous. If the Gibbs energy is negative, the process is spontaneous, and if it is positive, the process is non-spontaneous.


In what way will the gibbs free energy always be negative?

The Gibbs free energy will always be negative for a spontaneous reaction at constant temperature and pressure. This suggests that the reaction is thermodynamically favorable and can proceed without the input of external energy.


What are slowed reactions?

Chemical reactions that have high activation energy, with multiple intermediates and transitions states that have higher activation energy than the initial requirement, but which still have a negative Gibbs free energy change.


Is Gibbs free energy constant?

In general Gibbs free energy is NOT constant. Gibbs free energy can be translated into chemical potential and differences in chemical potential are what drive changes - whether it be chemical reactions, phase changes, diffusion, osmosis, heat exchange or some other thermodynamic function.


Under what conditions is G for a reaction always positive?

When H is positive and S is negative


What property characterizes a spontaneous redox reaction?

A positive sum of the two half-reactions' standard potentials