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I am uncertain at what specific date Justus von Liebig made the discovery. However, it wasn't until 1842 that Sir John Lawes outlined a method of treating phosphate rock with sulfuric acid to produce superphosphate, an effective fertilizer, and the start of the modern chemical fertilizer industry began.

Considering that Justus von Liebig was born in 1803 (he died in 1873). it is safe to say that he made the discovery sometime between 1824 and 1842.

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14y ago

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