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Electronegativity increases as you go from the bottom left corner of the Periodic Table to the upper right corner. The element with the lowest electronegativity is thus francium (Fr). However, this element is radioactive, and so generally the least electronegative element that you can really use is cesium (Cs). Generally speaking, this whole first column (the alkali metals) all have very low electronegativities, but the lower down the column, the lower the electronegativity.

(Francium may not be the least electronegative element due to the relativistic effects, which is evident from its ionization energy (> Cs) and standard electrode potential (This element is francium (Fr).

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