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Iridium wins when the density is calculated using the "space lattice" method, which is considered to be more accurate, when comparing it to Osmium.

An atom of Iridium has 77 protons, 77 electrons and 115 neutrons. At.wt. 192.22

An atom of Osmium has 76 protons, 76 elections and 114 neutrons. At. wt. 190.2

Osmium has a crystal structure that is "Hexagonal"

Iridium is a "Cubic face centred" crystal.

This crystal structure is how the atoms align with each other to form the material itself.

A good example to understand this is with Carbon. A very dense and very hard form is DIAMOND where the carbon atoms are very tightly and closely bonded together. A very soft form is GRAPHITE, where the carbons atoms are very loosely packed and easily parted from each other.

The Iridium structure's "space lattice" is more compact than that of Osmium such that more protons, neutrons and electrons fit into a unit volume and thus it is denser.

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