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Atomic number is a measure of protons and electrons. extra or less Neutrons are what make an isotope and are not included in atomic number. therefore element with the highest atomic number will also be the isotope with the highest atomic number. on my Periodic Table it is lawrencium at 103. (note although this might have extra neutrons making it an isotope, it will always have the same atomic number - atomic number isn't what determines an isotope it is mass number)

if you meant mass number (which is what determines an isotope), you can subtract the atomic number from the mass number to find out how many neutrons there are and determine whether it is an isotope or not

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