It is necessary to standardize a solution of NaOH using a primary standard like KHP because primary standards are highly pure and have a known exact mass. This allows for accurate and precise determination of the concentration of the NaOH solution, ensuring reliable and consistent results in experiments.
primary standard solution is prepared by direct measurements of the mass of solute and the volume of solution.whereas, a secondary standard solution is a solution whose concentration can't be determined directly from weight of solute and volume of solution, the concentration must be determined by analysis of the solution itself.
Because NaOH is hygroscopic, meaning it absorbs water from the air, NaOH cannot be accurately weighed. To standardize 0.1 M NaOH, a solution is made to an approximate concentration of 0.1 M and then standardized by titrating an accurately weighed quantity of a primary standard.
To standardize an HCl solution with a primary standard Na2CO3 solution, first, prepare a Na2CO3 solution of known concentration. Then, titrate the Na2CO3 solution with the HCl solution using a suitable indicator until the equivalence point is reached. From the volume of HCl solution used and the known concentration of Na2CO3, you can calculate the exact concentration of the HCl solution.
No, borax is not considered a primary standard. Primary standards are highly pure reagents that can be used to standardize solutions for volumetric analysis, while borax is typically used as a secondary standard for acid-base titrations.
To standardize 0.5 M HCl, you would typically titrate it using a primary standard solution such as sodium carbonate (Na2CO3). By titrating a known volume of the HCl with the sodium carbonate solution and using the mole ratio between the two, you can calculate the exact concentration of the HCl solution. This process ensures that the concentration of the 0.5 M HCl is accurate for future use in experiments.
primary standard solution is prepared by direct measurements of the mass of solute and the volume of solution.whereas, a secondary standard solution is a solution whose concentration can't be determined directly from weight of solute and volume of solution, the concentration must be determined by analysis of the solution itself.
No, sodium thiosulfate solution is not typically considered a primary standard. It is commonly used as a titrant in redox titrations rather than as a primary standard due to its susceptibility to oxidation by air. Primary standards are typically pure, stable compounds that can be used to standardize solutions.
Because NaOH is hygroscopic, meaning it absorbs water from the air, NaOH cannot be accurately weighed. To standardize 0.1 M NaOH, a solution is made to an approximate concentration of 0.1 M and then standardized by titrating an accurately weighed quantity of a primary standard.
To standardize an HCl solution with a primary standard Na2CO3 solution, first, prepare a Na2CO3 solution of known concentration. Then, titrate the Na2CO3 solution with the HCl solution using a suitable indicator until the equivalence point is reached. From the volume of HCl solution used and the known concentration of Na2CO3, you can calculate the exact concentration of the HCl solution.
No, borax is not considered a primary standard. Primary standards are highly pure reagents that can be used to standardize solutions for volumetric analysis, while borax is typically used as a secondary standard for acid-base titrations.
sodium hydroxide is a secondary standard because it absorb the moisture from the air and its concentration will change
To standardize 0.5 M HCl, you would typically titrate it using a primary standard solution such as sodium carbonate (Na2CO3). By titrating a known volume of the HCl with the sodium carbonate solution and using the mole ratio between the two, you can calculate the exact concentration of the HCl solution. This process ensures that the concentration of the 0.5 M HCl is accurate for future use in experiments.
A primary standard solution is generally a solution prepared and certified by an authorized and specialized institution (for example: NIST - National Institute for Standards and Technology).
Sodium Carbonate (Na2CO3) is most commonly used to standardise acids as it is non-hygroscopic (doesn't absorb water from the atmosphere).Oxalic Acid (HOOCCOOH or H2C2O4) used to standardise bases
Titrate it with a primary standard
NaOH
The two main types of standard solutions are primary standard solutions, which are highly pure and stable substances that can be used to make precise titrations, and secondary standard solutions, which are solutions prepared using a primary standard solution as a reference for their concentration.