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Acetic acid is too weak an acid to provide the desired acidity in the solution, The reaction at room temperature is slow because of the equilibrium nature of this reaction. CO2 is highly soluble in water and thus heating removes all dissolved carbondioxide out of the solution driving the reaction in forward direction.
2KMnO4 + 5 H2C2O4 + 3H2SO4 = 2MnSO4 + K2SO4 + 10 CO2 + 8H2O
2MnO4¯ + 10 C2O42¯+ 16H+ = 2Mn2+ + 10 CO2 + 8H2O
at low temperature, the reduction of permanganate may not be complete producing Mn(III) (in the form [Mn(C2O4)3]3-).This complex however breaks on heating and hence reaction proceeds smoothly.
What else can I help you with?
Why is the vinegar diluted before titration?
1. The advantage in diluting the solution before titration is that it allows for greater accuracy in the titration; this is because the color change in the solution is easier to observe if it is a dilute solution.
Why potassium oxalate is acidified before titration?
If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.
Why do we heat KSCN Fe solution befor titration with EDTA?
Heating the KSCN Fe solution before titration with EDTA helps to break down any complex formations involving iron and potassium thiocyanate. This ensures that the titration accurately measures the amount of iron present in the solution by allowing EDTA to chelate with the iron ions more effectively.
What is the scout titration?
The scout titration is a preliminary titration carried out to estimate the approximate endpoint in a titration experiment before performing the actual titration. It helps in determining the approximate volume of titrant required for the main titration to avoid overshooting the endpoint.
Why the solution is boiled before titration?
Boiling the solution before titration helps to remove any dissolved gases that may interfere with the titration process. Additionally, heating the solution can help to dissolve the solute more effectively and improve the accuracy of the titration results.
Why is the vinegar diluted before titration?
1. The advantage in diluting the solution before titration is that it allows for greater accuracy in the titration; this is because the color change in the solution is easier to observe if it is a dilute solution.
Why potassium oxalate is acidified before titration?
If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.
Why do we heat KSCN Fe solution befor titration with EDTA?
Heating the KSCN Fe solution before titration with EDTA helps to break down any complex formations involving iron and potassium thiocyanate. This ensures that the titration accurately measures the amount of iron present in the solution by allowing EDTA to chelate with the iron ions more effectively.
Why is potassium iodide added to an organic layer before titration with sodium thiosulfate?
Potassium iodide is added to an organic layer before titration with sodium thiosulfate to facilitate the formation of iodine from the oxidation of iodide ions. This iodine can then be titrated with sodium thiosulfate, allowing for the quantitative analysis of oxidizing agents present in the organic layer. The reaction between iodine and thiosulfate is well-defined and allows for accurate determination of the concentration of the oxidizing species.
What is the scout titration?
The scout titration is a preliminary titration carried out to estimate the approximate endpoint in a titration experiment before performing the actual titration. It helps in determining the approximate volume of titrant required for the main titration to avoid overshooting the endpoint.
Why the solution is boiled before titration?
Boiling the solution before titration helps to remove any dissolved gases that may interfere with the titration process. Additionally, heating the solution can help to dissolve the solute more effectively and improve the accuracy of the titration results.
What is pilot titration?
Pilot titration is a preliminary test to determine the approximate endpoint of a titration process before conducting the actual titration. It helps in estimating the volume of titrant needed for the main titration, ensuring more accurate and efficient results. The data obtained from a pilot titration can help in planning and executing the main titration with greater precision.
Why heat citric acid before titration?
Heating citric acid before titration is done to help dissolve the solid citric acid more effectively in the solution. This ensures that the titration reaction occurs uniformly and the results are accurate. Additionally, heating can also help increase the rate of the reaction, making the titration process faster.
Why is it necessary to establish a blank titration before the reaction?
Establishing a blank titration allows you to account for any impurities or contaminants in the titration procedure or equipment, which could affect the accuracy of your results. By performing a blank titration, you can isolate the contribution of these factors and subtract them from your subsequent titration measurements to ensure the accuracy of your results.
Why is the outside of the burette wiped with paper towel before titration?
The outside of the burette is wiped with a paper towel before titration to ensure that any liquid droplets on the outer surface do not affect the accuracy of the titration by inadvertently entering the solution being titrated. This helps to prevent contamination and ensure precise measurements are obtained during the titration process.
Why is a solution containing a metal ion buffered before titration with EDTA?
Buffering the solution containing a metal ion before titration with EDTA helps maintain a constant pH, which is crucial for the accuracy and precision of the titration. The buffering prevents large pH changes that could affect the formation of metal-EDTA complexes and lead to errors in the titration results.
Why before doing titration conical flask is not rinsed?
The conical flask is not rinsed before performing titration because doing so could dilute the solution and alter the concentration, affecting the accuracy of the titration. It is important to maintain the concentration of the solution as accurately as possible for precise results.
