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What is the difference between iodometric titration and iodimetric titration?
Iodometric titration involves the titration of iodine with a reducing agent, while iodimetric titration involves the titration of iodide with an oxidizing agent. In iodometric titration, iodine is detected by a starch indicator to determine the end point, while in iodimetric titration, iodide ion concentration is determined by titration with a standard solution of an oxidizing agent.
What is the effect of adding the sulfuric acid before KI in iodometric titration?
Adding sulfuric acid before KI in an iodometric titration helps to acidify the solution and prevent the premature oxidation of iodide ions to iodine. This ensures that the iodide ions react with the analyte (substance being tested) instead of being oxidized by any oxidizing agents present in the solution. Acidifying the solution also helps to stabilize the iodine formed during titration.
What is the usage of KCNS in a iodometric titration?
Some of the metal ion that is estimated (especially Cu2+) may get trapped within starch indicator. When KCNS is added, copper thiocyanate or Cu(CNS)2 complex is formed which then reacts with the KI added, giving correct results.
Why ki is added in coulometry titration?
Potassium iodide (KI) is added in coulometry titration to help facilitate the generation of iodine (I2) following the reduction of iodate ions (IO3-) in the sample solution. The produced iodine can then be titrated with a standardized thiosulfate solution to determine the amount of substance being analyzed. Additionally, KI acts as a stabilizer for iodine, preventing its premature reaction or volatilization.
Why you use KI solution in idiometric titration?
KI solution is commonly used in idiometric titrations because the presence of iodide ions allows for the detection of certain oxidizing agents through the formation of a characteristic color change with starch indicator. This method is particularly useful for determining the concentration of oxidizing agents such as chlorine or iodine in a sample solution.
What is the difference between iodometric titration and iodimetric titration?
Iodometric titration involves the titration of iodine with a reducing agent, while iodimetric titration involves the titration of iodide with an oxidizing agent. In iodometric titration, iodine is detected by a starch indicator to determine the end point, while in iodimetric titration, iodide ion concentration is determined by titration with a standard solution of an oxidizing agent.
Why KI is added in redox iodometric titration even in the presence of sodium thiosulfate as a reducing agent?
In iodometric titrations sodium thiosulfate is the titrant whereas the KI will reduce the analyte; eg: Cu2+ to Cu+. The I2 produced is then titrated by the sodium thiosulphate. Cu2+ + I- --> CuI + I3- I3- + 2 S2O32- ¾® 3 I- + S4O62- To answer your question: KI (reducing agent) is added to generate the iodine by the reduction of the analyte (Cu2+) The formed iodine is then back-titrated with thiosulfate (titrant) to determine the amount of analyte originally present. As you can see the KI and sodium thiosulfate serve two different purposes. KI improves solubility of Iodine
What is the effect of adding the sulfuric acid before KI in iodometric titration?
Adding sulfuric acid before KI in an iodometric titration helps to acidify the solution and prevent the premature oxidation of iodide ions to iodine. This ensures that the iodide ions react with the analyte (substance being tested) instead of being oxidized by any oxidizing agents present in the solution. Acidifying the solution also helps to stabilize the iodine formed during titration.
What is the usage of KCNS in a iodometric titration?
Some of the metal ion that is estimated (especially Cu2+) may get trapped within starch indicator. When KCNS is added, copper thiocyanate or Cu(CNS)2 complex is formed which then reacts with the KI added, giving correct results.
How the result will be affected if 0.1cm3 more aqueous CH3COOH and KI was added in iodometric titration?
There is no interference with results when already a correct abundancy of both were added. (pH < 5, and more than triple (molar) amount Iodide over the Oxidant)See also: 'Related questions' however.
Why ki is added in coulometry titration?
Potassium iodide (KI) is added in coulometry titration to help facilitate the generation of iodine (I2) following the reduction of iodate ions (IO3-) in the sample solution. The produced iodine can then be titrated with a standardized thiosulfate solution to determine the amount of substance being analyzed. Additionally, KI acts as a stabilizer for iodine, preventing its premature reaction or volatilization.
Why is acetic acid added to vitamin C in a titration reaction with KI and N bromosuccinimide?
Acetic acid is added in the titration reaction to provide the acidic conditions necessary for the reaction between KI and N-bromosuccinimide to occur effectively. The acidic medium helps to convert KI to iodine, which can then react with N-bromosuccinimide. This reaction is commonly used to determine the vitamin C content in a solution.
What test is used to determine if excess hypochlorous acid is present in the oxidation mixture?
KI
Why is an excess of KI used in determining the percent of copper in brass?
It might be because iodide and iodine is in an equilibrium: I2 + I- -> I3- That way formed iodine won't escape when an excess of iodide is used.
Why you use KI solution in idiometric titration?
KI solution is commonly used in idiometric titrations because the presence of iodide ions allows for the detection of certain oxidizing agents through the formation of a characteristic color change with starch indicator. This method is particularly useful for determining the concentration of oxidizing agents such as chlorine or iodine in a sample solution.
What is the role of KI in the estimation of aniline?
ki is added to liberate iodine gas . this liberated iodine gas was then titrated with sodium thiosulphate to give a permanent white precipitate. this white precipitate indicates the endpoint of the titration..
Why potassium thiocyanate is added in the titration of sodium thiosulphate with copper?
On addition of the KI to your copper (II) solution, you formed Copper (I) iodine solid and produced the tri-iodide ion. It is the tri-iodide ion that you are titrating with the sodium thiosulfate. The tri-iodine ion is what itercalates into the starch molecules to form the dark blue color you are using as an end point in the titration. Some the the tri-iodide ion formed will adsorb to the surface of the solid copper (I) iodine formed. This must be desorbed for a complete titration. The addition of the potassium thiocyanate, displaces the adsorbed tri-iodine ion, and liberates it for titration.
