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Benzaldehyde is the simplest aromatic aldehyde. The oxidizing agent used in Fehling's solution is not strong enough to oxidize the aromatic ring. Therefore Benzaldehyde doesn't show Fehling's test. I hope it helped :)

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11y ago
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12y ago

fehling solution B is alkaline soution complex with sod. pot. tartrate in the presence of alkali benzaldehyde give cannizaro reaction.

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Q: Why benzaldehyde doesn't give fehling solution test?
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Does formalin give positive Fehling's solution test?

Formalin gives a positive Fehling's solution test.


Why dont polysaccharides give a positive test with Fehling's solution?

Fehling test is only suitable for reducing sugars, that means, monosaccharides in its open form with an aldehyd available. Polysacchardes have the aldehydes in a acetal form and they can not react


Why starch does not give with fehling test?

Starch doesnot give positive result for Fehling's test as it does not have a free hemiacetal group


What is the function of Fehling's test?

Fehling's test is used to differentiate between aldehyde and ketones group. An aldehyde group will react with Fehling's reagent to give cuprous oxide resulting in a red precipitate. A Ketone group will not react with Fehling's reagent.


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Benzaldehyde has a benzene ring where formaldehyde has a hydrogen atom. (C6H5CHO as opposed to HCHO). Formaldehyde is used as a biocide and a disinfectant. It is a nasty substance and may be a carcinogen. Benzaldehyde on the other hand is used as a food additive to give an almond flavour.


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All aldehydes give a positive result with Fehling's test. All ketones give negative results.


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Due to absence of free hemiacetal group


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