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The trihalide ions I3- and Br3- are well known. They are the smallest members of groups of polyhalide ions In- and Brn- The Iodine groups is the best knwn.

In comparison only F3- has been isolated and that has proved unstable.

A simple explanation is that bromine and iodine have d orbitals which can take part in the bonding wheres fluorine does not. However these compounds have caused a lot of debate and there is no clear cut concensus on the bonding mechanism. If you are really inetested in this follow links to hypervalency, three center 4 electron bonds, Musher.

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