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The transition elements form complexes because they are able to accept pairs of electrons from donor molecules or ions to form dative covalent bonds. The reason they can accept pairs of electrons is because they have a number of empty orbitals in the d subshells.

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12y ago

The d-block elements being smaller in size and have high electropositive density,it consists of (n-1)d free orbitals to accepts the free electrons from the ligand and it forms complexes easily.

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Q: Why do the d-block elements form complexes?
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