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Ammonium Nitrate acts as an oxidizer to the reaction. Ammonium Chloride merely provides Cl- as a catalyst to the reaction. The water in the spit begins to decompose the Ammonium Nitrate, which produces Nitrous Oxide and water vapor. The water vapor decomposes more Ammonium Nitrate, creating an autocatalyitic effect. The heat provided from the decomposition ignites the zinc, creating more heat, which decomposes the Ammonium Nitrate at a faster rate, producing more gas more rapidly. The overall formula is:

Zn(s) + NH4NO3(s) → N2(g) + ZnO(s) + 2 H2O(g)

*Note* Sodium Chloride may also be used in place of Ammonium Chloride.

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Q: Why does mixing zinc powder ammonium chloride ammonium nitrate and spit create fire?
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