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There are 2 reasons for using high pressure oxygen in bomb calorimeter. The 1st is that we need enough oxygen for a complete combustion in a very small volume. To do that the oxidant pressure must be high. The typical air ratios in a bomb calorimeter are between 4 and 9.

The 2nd reason is that we want to measure the high calorific value of a fuel. Thus the water produced from the combustion must be in liquid form. For a certain temperature, the higher the vapor pressure, the higher the liquid water percentage. So, the higher the total pressure (25 atm), the higher the partial vapor pressure.

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Q: Why high pressure oxygen is used in bomb calorimeter?
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