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Why iron rod loos its shiny and rusted when in kept in open air?

Updated: 4/28/2022

Wiki User

∙ 11y ago

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as oxide of iron is formed on the nail in contact with the environment

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∙ 11y ago

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Q: Why iron rod loos its shiny and rusted when in kept in open air?

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Why can't tertiary alcohols be oxidized?

Simple answer ... you need at least one hydrogen attached to carbinol carbon. in other words, you have a hydrogen on the oxygen to give you the hydroxyl group that is attached to the carbinol carbon, but you also need a hydrogen coming off that carbon. The reason - your reagent, such as chromic acid, joins with the alcohol at the position of the hydroxyl group, which leads to an H2O molecule being shot off. The chromic acid provides the -OH of that water, but takes the H off the hydroxyl group to get the 2nd hydrogen atom. You would now have a chromate ester + water. The water then takes off a hydrogen atom attached to the carbinol carbon, which leaves the electrons to form a double bond with the Oxygen atom. Without the hydrogen attached to the carbinol carbon ... like in a tertiary alcohol ... oxidation could only take place by breaking carbon-carbon bonds, which requires severe conditions. Even if this did happen, you would get a mixture of products.

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