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Chemicals have their own intrinsic properties and melting point is one of them. Carboxylic acids tend to raise the melting point of substances as compared to their nitrile kin by increasing the polar interactions between like molecules. These interactions require greater energy to overcome to achieve the liquid state, which to the observer shows up as higher melting points. It just happens that room temperature falls between when benzonitrile melts and when benzoic acid melts.

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