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Hexane is exerts a large amount of dispertion forces and thus it is a good solvent for large molecules. You see, the larger a molecule is the more dispertion forces it has.

What does all this mean? Well, if two molecules exert the same kind of forces the are miscible. And you guessed it right, oils have a great deal of dispertion forces. Thus hexane is good at dissolving oil stains.

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Q: Why is hexane good at removing oil stains?
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because there is oil on your skin right? so the soap when you rub it on the shirt the oil is rinsed off by the water


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