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neutral K atom has 19 electrons with electronic configuration of 2,8,8,1 but K +1 has 18 electrons with electronic configuration of 2,8,8. Thus removing an electron from neutral k atom means only 3 energy shells in k ion as compared to 4 shells in a neutral k atom. Lesser shells means more close to nucleus, thus more attraction by the nucleus which means smaller atomic size. It has one less shell containing electrons.

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14y ago
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12y ago

That's because K atom is the neutral atomic form, having 19 protons in the core and 19 electrons, but the K+ ion has 19 protons (19 positive charge) and only 18 electron (18 negative charge). This means, the effective attraction of the electrons is bigger, because not one proton has to attract one electron, but 19/18 proton has to attract one electron. More effective attraction pulls the remaining 18 electron closer to the positive core, making the potassium and all the other alkali metal (Li, Na, K, Rb, Cs, Fr) ions' electron cloud smaller. And also that's the reason for the halogenic negative ions (F,Cl,Br,I) to be bigger than the atom: they have more negative charge, so the electrons are not as attracted to the core as they are in the atomic form.

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Q: Why is potassium ion smaller than potassium atom?
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