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I'm no chemist but I'm pretty sure it has to do with the orbitals, they hybridized to form sp3d2 orbitals which then can bond 6 fluorines, once you get past the first few atoms in the Periodic Table the orbitals get pretty big and odd so the standard answers like having 8 valence electrons no longer hold completely.

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Q: Why is sulphur able to form 6 covalent bonds in sf6?
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