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Adjusting the pH to 10 before complexometric titration helps ensure the formation of a stable metal-ligand complex. At pH 10, metal ions form strong complexes with the chelating agent (usually EDTA) without interference from other ions. This pH also helps maintain the reaction conditions constant and improves the accuracy of the titration results.
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Why PH 10 is maintain in complexometric titration?
A pH of 10 is maintained in complexometric titrations because it ensures the stability of metal-ligand complexes. At this pH, the metal ion forms stable complexes with the titrant (EDTA) while minimizing interference from other ions. Additionally, a pH of 10 helps to maintain appropriate solubility of the metal-ligand complexes for accurate endpoint detection.
What kind of titrations are possible with phenolphthalein as indicator?
Phenolphthalein is commonly used in acid-base titrations because it changes color at a pH range of 8.2-10, making it ideal for determining the endpoint of the titration. It is also used in complexometric titrations to detect the presence of metal ions, as phenolphthalein can form colored complexes with certain metals.
What is the pH at the second equivalence point in a titration?
The pH at the second equivalence point in a titration is typically around 9 to 10.
What is the purpose for using phenolphthalein for an acid base titration?
Phenolphthalein is used as an indicator in acid-base titrations because it changes color at a specific pH range. In an acid-base titration, phenolphthalein changes from colorless to pink when the solution reaches a pH around 8.2-10, indicating the endpoint of the titration. This allows for a visual indication of when the reaction is complete.
Why is back titration required in the volhard method?
This method uses a back titration with potassium thiocyanate to determine the concentration of chloride ions in a solution.Before the titration an excess volume of a standardized silver nitrate solution is added to the solution containing chloride ions, forming a precipitate of silver chloride (AgCl). The term 'excess' is used as the moles of silver nitrate added are known to exceed the moles of sodium chloride present in the sample so that all the chloride ions present will react.Ag+ + Cl- AgCl(s) (Ksp = 1.70 × 10−10)Excess WhiteExcess of Ag+ is back titrated with SCN-.
Why PH 10 is maintain in complexometric titration?
A pH of 10 is maintained in complexometric titrations because it ensures the stability of metal-ligand complexes. At this pH, the metal ion forms stable complexes with the titrant (EDTA) while minimizing interference from other ions. Additionally, a pH of 10 helps to maintain appropriate solubility of the metal-ligand complexes for accurate endpoint detection.
Why The pH range is to be maintained around 9-10 in EDTA complexometric titration?
In EDTA complexometric titration, maintaining the pH around 9-10 is crucial because this range ensures optimal deprotonation of metal ions and the effective formation of stable metal-EDTA complexes. At this pH, most metal ions, such as calcium and magnesium, are present in their ionic forms, allowing for better complexation. Additionally, a higher pH helps minimize the interference from hydrogen ions, which could otherwise compete with metal ions for complexation with EDTA. Overall, this pH range enhances the accuracy and reliability of the titration results.
What is the need for an ammonical buffer solution in the determination of hardness of water by edta titration?
during the complexometric titration using edta it is very necessary to maintain the ph of the solution near about 10 so we use ammonium chloride buffer if we will not use this buffer dring the titration ph of sol. will ho lower side
What kind of titrations are possible with phenolphthalein as indicator?
Phenolphthalein is commonly used in acid-base titrations because it changes color at a pH range of 8.2-10, making it ideal for determining the endpoint of the titration. It is also used in complexometric titrations to detect the presence of metal ions, as phenolphthalein can form colored complexes with certain metals.
What is the pH at the second equivalence point in a titration?
The pH at the second equivalence point in a titration is typically around 9 to 10.
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10 degrees before top dead center. only the 87-91 can be adjusted. the92 and up are not adjustible
What is the purpose for using phenolphthalein for an acid base titration?
Phenolphthalein is used as an indicator in acid-base titrations because it changes color at a specific pH range. In an acid-base titration, phenolphthalein changes from colorless to pink when the solution reaches a pH around 8.2-10, indicating the endpoint of the titration. This allows for a visual indication of when the reaction is complete.
Why is back titration required in the volhard method?
This method uses a back titration with potassium thiocyanate to determine the concentration of chloride ions in a solution.Before the titration an excess volume of a standardized silver nitrate solution is added to the solution containing chloride ions, forming a precipitate of silver chloride (AgCl). The term 'excess' is used as the moles of silver nitrate added are known to exceed the moles of sodium chloride present in the sample so that all the chloride ions present will react.Ag+ + Cl- AgCl(s) (Ksp = 1.70 × 10−10)Excess WhiteExcess of Ag+ is back titrated with SCN-.
Why is phenolphthalein is used in titration experiment?
it is used as an acid-base indicator
What is the function of phenolphthalein in titration?
Phenolphthalein is a pH indicator commonly used in acid-base titrations. It changes color in a specific pH range (around pH 8.2 to 10), allowing the endpoint of the titration to be visually determined. This makes it easier to accurately measure the amount of titrant required to reach the equivalence point.
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Why is NH3-NH4CL buffer preferred in edta titration for determination of mg?
The NH3-NH4Cl buffer is preferred in EDTA titration for the determination of magnesium because it helps maintain a relatively constant pH (around 10), which is necessary for the formation of stable complexes between EDTA and magnesium ions. The NH4Cl helps prevent the precipitation of magnesium hydroxide, which could interfere with the titration.
