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Water is only at the bottom of a mixture of immiscible liquids if it is the densest liquid. If the other liquid is denser than water, water will be at the top, as would occur in a mixture of water and Mercury in a beaker.

The density of water is 1.00 g/ml, mercury is 13.5 g/ml and olive oil is about 0.85 g/ml.

Therefore water will be on the bottom of an oil/water mixture, but will be on the top of a mercury/water mixture.

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