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Energy difference in N2 2s orbital and 2Px orbital is very low due to which they mix with each other.2s give its energy to 2Px, 2Px gain more energy and became unstable and increase its energy, and jump above on the 2Pz, 2Py orbitals in MOT diagram.

now ALL 4 atomic orbitals i.e 2s sigma, 2s sigma star ,2Px sigma,2Px sigma star donot have thier own pure characters. other orbitals donot take part in mixing

NOTE:

this phenomena is for elements having atomic number up to 7

OXYGEN have atomic number 8. it energy differences b/w orbitals is large.That's why its MOT diagram is different.

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