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Vitriol is Nothing but Copper Sulphate. Both copper and silver are below the reactant level. Refer the Activity Series of Metals on your Periodic Table, The copper and silver will be below the arrow. So The least reactant for which when those 2 are mixed no reaction occurs.

So Silver does not decolourising the blue colour of aqueous blue vitriol

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Q: Why silver does not decolourising the blue colour of aqueous blue vitriol?
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