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Tertiary alkyl halides are more reactive than primary alkyl halides because the carbon in a tertiary alkyl halide is more substitued and more stable due to hyperconjugation and steric hindrance. This makes the C-X bond weaker in tertiary alkyl halides, making them more reactive towards nucleophilic substitution reactions.
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Why tertiary carbonium ions are more stable than the primary and secondary carbonium ions?
Tertiary carbonium ions are more stable because they have more neighboring alkyl groups that can donate electron density through hyperconjugation, stabilizing the positive charge. In contrast, primary and secondary carbonium ions have fewer alkyl groups available for stabilization, making them less stable.
What is the reaction between alcoholic KOH and alkyl halide?
Alcoholic KOH (potassium hydroxide in alcohol) reacts with an alkyl halide through an elimination reaction called the E2 mechanism to form an alkene. The alkyl halide undergoes deprotonation by the strong base (KOH) and elimination of the halogen atom to generate the alkene product.
What is friedal craft reaction?
when alkyle helide or acyle helide react with benzene ring and there is elemanition of h ATM such reaction called friedal craft reaction ............... there is 2 types 1...... friedal craft Alkylation 2...... friedal craft Acylation
Why tertiary carbonium ions are more stable than the primary and secondary carbonium ions?
Tertiary carbonium ions are more stable because they have more neighboring alkyl groups that can donate electron density through hyperconjugation, stabilizing the positive charge. In contrast, primary and secondary carbonium ions have fewer alkyl groups available for stabilization, making them less stable.
When alkyl halide react with kCN form cynide but alkyle halide react with AgCN form iso cynide why?
In the presence of potassium cyanide (KCN), alkyl halides typically undergo an SN2 reaction to form nitriles due to the strong nucleophilicity of cyanide ion. However, when reacting with silver cyanide (AgCN), the reaction mechanism favors an SN1 pathway due to the solubility of AgCN in polar solvents, resulting in the formation of isocyanides (also known as isonitriles) instead of nitriles.
Is alkyle group is electron withdrawing?
Alkyl groups are generally electron donating due to their inductive effect, where they push electron density towards the rest of the molecule. This is because alkyl groups are less electronegative than carbon and hydrogen, leading to a slight positive charge that can stabilize adjacent negative charges.
What is alkyle?
Alkylation is a chemical process involving carbon atoms. In refineries, this is done to add octane to gasoline by introducing hydrocarbons to the fuel.
How did Poison Gas work?
It depends on the type of gas used, mustard gas was one of the most common types and this attached an alkyle group to guanine nucleotides in DNA. if these guanines were in genes then transcription stopped and replication of the DNA was stopped (or went seriously wrong) this normal lead to apoptosis (programed cell death) but depending on what genes were mutated and the type of cell attacked then it could cause cancer.
What is the reaction between alcoholic KOH and alkyl halide?
Alcoholic KOH (potassium hydroxide in alcohol) reacts with an alkyl halide through an elimination reaction called the E2 mechanism to form an alkene. The alkyl halide undergoes deprotonation by the strong base (KOH) and elimination of the halogen atom to generate the alkene product.
What is friedal craft reaction?
when alkyle helide or acyle helide react with benzene ring and there is elemanition of h ATM such reaction called friedal craft reaction ............... there is 2 types 1...... friedal craft Alkylation 2...... friedal craft Acylation
