Because the +R effect of the haloarene, tends to oppose the -I effect, and hence the deactivation is lesser at the ortho and para positions, compared to any other position (like the meta position). So they tend to be o-p directing.
electrophilic substitution. and UV light or heat is required to all the reaction to proceed
As there is an availability of lone pair of electrons on chlorine, it directs the benzene ring towards electrophilic substitution at ortho and para positions.. When we will draw the resonating structures of chloro benzene,we will see that negative charge resides at orho and para positions..
A nucleophile attacks an electrophilic site and replaces a leaving group. e.g. OH- attacks R-Br to give R-OH.
That's an electrophilic aromatic substitution reaction ad will replace a hydrogen with a NO2 group on the ring
No, Haloarenes are less reactive than benzene towards electrophillic substitution reaction. This is because the halogen atom attached to benzene ring in haloarenesis slightly deactivating and orthoand para directing. so attack can only take place at orthoand para. Also the halogen atom in Haloarenesdue to its -I effect has some tendancyto withdraw electrons from the benzene ring and hence making it deactivating.Since the ring gets deactivated as compared to benzene, haloarenesare less reactive than benzene in electrophillicsubstituionreaction.
i think the question is wrong.benzene doesn't respond nucleophilic substitution respond electrophilic substitution it is electrophilic then due to resonance there is a partial double bond between carbon of benzene and halogens.so halobenzenes are chemically inert towards electrophilic substitution.
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electrophilic substitution. and UV light or heat is required to all the reaction to proceed
the electron in benzene are delocalised making d ring to be elctron rich,thereby undergoing electrophilic substitution.benzene cannot undergo nucleophillic substitution,it can only undergo if it is substituted with an electron withdrawing group
When a positive ion (electrophile) attacks on a pi bond or partially negative carbon atom and replace H as a positive ion then it is electrophilic substitution reaction.
As there is an availability of lone pair of electrons on chlorine, it directs the benzene ring towards electrophilic substitution at ortho and para positions.. When we will draw the resonating structures of chloro benzene,we will see that negative charge resides at orho and para positions..
A nucleophile attacks an electrophilic site and replaces a leaving group. e.g. OH- attacks R-Br to give R-OH.
The Electrophilic Addition Reaction is when the attacking species during the addition reaction is"Electrophile", it is called "electrophilic addition reaction". Examine: (+) (-) (+) (-) (+) (-) CH2Br-CH2BràH2C-CH2+BrBr-àH2C=CH2+Br2-
That's an electrophilic aromatic substitution reaction ad will replace a hydrogen with a NO2 group on the ring
No, Haloarenes are less reactive than benzene towards electrophillic substitution reaction. This is because the halogen atom attached to benzene ring in haloarenesis slightly deactivating and orthoand para directing. so attack can only take place at orthoand para. Also the halogen atom in Haloarenesdue to its -I effect has some tendancyto withdraw electrons from the benzene ring and hence making it deactivating.Since the ring gets deactivated as compared to benzene, haloarenesare less reactive than benzene in electrophillicsubstituionreaction.
jaom maran
Resorcinol is used as the complexing agent to provide the color reaction, although the exact nature of the colored product is not known. Since resorcinol favors electrophilic aromatic substitution, the reaction may be similar to the Molisch Test.