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What are 5 examples of lithium?

The alkali metals (Li, Na, K etc.) and the alkaline earth metals (Mg and Ca, together with Zn) are good reducing agents, the former being stronger than the latter. Sodium, for example, reduces elemental chlorine to chloride anion (sodium is oxidized to its cation), as do the other metals under varying conditions. In a similar fashion these same metals reduce the carbon-halogen bonds of alkyl halides. The halogen is converted to halide anion, and the carbon bonds to the metal (the carbon has carbanionic character). Halide reactivity increases in the order: Cl < Br < I. The following equations illustrate these reactions for the commonly used metals lithium and magnesium (R may be hydrogen or alkyl groups in any combination). The alkyl magnesium halides described in the second reaction are called Grignard Reagents after the French chemist, Victor Grignard, who discovered them. The other metals mentioned above react in a similar manner, but the two shown here are the most widely used. Although the formulas drawn here for the alkyl lithium and Grignard reagents reflect the stoichiometry of the reactions and are widely used in the chemical literature, they do not accurately depict the structural nature of these remarkable substances. Mixtures of polymeric and other associated and complexed species are in equilibrium under the conditions normally used for their preparation.R3C-X + 2Li --> R3C-Li + LiX An Alkyl Lithium ReagentR3C-X + Mg --> R3C-MgX A Grignard ReagentThe metals referred to here are insoluble in most organic solvents, hence these reactions are clearly heterogeneous, i.e. take place on the metal surface. The conditions necessary to achieve a successful reaction are critical.First, the metal must be clean and finely divided so as to provide the largest possible surface area for reaction.Second, a suitable solvent must be used. For alkyl lithium formation pentane, hexane or ethyl ether may be used; but ethyl ether or THF are essential for Grignard reagent formation.Third, since these organometallic compounds are very reactive, contaminants such as water, alcohols and oxygen must be avoided.These reactions are obviously substitution reactions, but they cannot be classified as nucleophilic substitutions, as were the earlier reactions of alkyl halides. Because the functional carbon atom has been reduced, the polarity of the resulting functional group is inverted (an originally electrophilic carbon becomes nucleophilic). This change, shown below, makes alkyl lithium and Grignard reagents unique and useful reactants in synthesis.


What type of reaction is shown in this thermochemical equation A plus B plus Heat -- C plus D?

The reaction shown in the thermochemical equation is an exothermic reaction. This is because heat is a reactant (on the left side of the equation) and is released during the reaction.


Which of the molecules in this chemical equation shown is a reactanct?

The molecules on the left side of the arrow in a chemical equation are the reactants. They are the starting substances that undergo chemical reactions to form products.


What is heat of reaction and enthalpy of reaction?

Heat of reaction and enthalpy of reaction are the same thing. Enthalpy, or the heat transfer, cannot be measured, however we can measure the CHANGE of enthalpy which is shown by a value of &#8710;H. This measured in kilojoules per mole of reactant. (KJ/mol)This value may be positive or negative. For endothermic reactions (which absorb heat), the &#8710;H value is always positive. For exothermic, where heat is released, the value is negative.


Why KMnO4 used in TLC?

KMnO4 is used in TLC (Thin Layer Chromatography) as a staining reagent for the detection of alkenes and alkynes. It reacts with the double or triple bonds in the compounds, forming a brown precipitate that allows for easy visualization of the separated compounds on the TLC plate.

Related Questions

What are 5 examples of lithium?

The alkali metals (Li, Na, K etc.) and the alkaline earth metals (Mg and Ca, together with Zn) are good reducing agents, the former being stronger than the latter. Sodium, for example, reduces elemental chlorine to chloride anion (sodium is oxidized to its cation), as do the other metals under varying conditions. In a similar fashion these same metals reduce the carbon-halogen bonds of alkyl halides. The halogen is converted to halide anion, and the carbon bonds to the metal (the carbon has carbanionic character). Halide reactivity increases in the order: Cl < Br < I. The following equations illustrate these reactions for the commonly used metals lithium and magnesium (R may be hydrogen or alkyl groups in any combination). The alkyl magnesium halides described in the second reaction are called Grignard Reagents after the French chemist, Victor Grignard, who discovered them. The other metals mentioned above react in a similar manner, but the two shown here are the most widely used. Although the formulas drawn here for the alkyl lithium and Grignard reagents reflect the stoichiometry of the reactions and are widely used in the chemical literature, they do not accurately depict the structural nature of these remarkable substances. Mixtures of polymeric and other associated and complexed species are in equilibrium under the conditions normally used for their preparation.R3C-X + 2Li --> R3C-Li + LiX An Alkyl Lithium ReagentR3C-X + Mg --> R3C-MgX A Grignard ReagentThe metals referred to here are insoluble in most organic solvents, hence these reactions are clearly heterogeneous, i.e. take place on the metal surface. The conditions necessary to achieve a successful reaction are critical.First, the metal must be clean and finely divided so as to provide the largest possible surface area for reaction.Second, a suitable solvent must be used. For alkyl lithium formation pentane, hexane or ethyl ether may be used; but ethyl ether or THF are essential for Grignard reagent formation.Third, since these organometallic compounds are very reactive, contaminants such as water, alcohols and oxygen must be avoided.These reactions are obviously substitution reactions, but they cannot be classified as nucleophilic substitutions, as were the earlier reactions of alkyl halides. Because the functional carbon atom has been reduced, the polarity of the resulting functional group is inverted (an originally electrophilic carbon becomes nucleophilic). This change, shown below, makes alkyl lithium and Grignard reagents unique and useful reactants in synthesis.


What chemical reactions shown from H2o O2 H2O2?

The simplified chemical reaction is:H2 + O2 = H2O2


What type of reaction is shown in this thermochemical equation A plus B plus Heat -- C plus D?

The reaction shown in the thermochemical equation is an exothermic reaction. This is because heat is a reactant (on the left side of the equation) and is released during the reaction.


Hydrogen and chlorine combine to produce hydrochloric acid as shown in the equation below H2 C12 - 2HC1 is this reaction exothermic or endothermic?

The reaction between hydrogen and chlorine to form hydrochloric acid is exothermic, meaning it releases heat as it proceeds. This can be inferred from the fact that the products have lower energy than the reactants, resulting in a release of energy in the form of heat.


What happens to redox reaction when it is shown as half-reactions?

The redox reaction is split into its oxidation part and its reduction part.


What happens to redox reaction when it shown as half reactions?

The redox reaction is split into its oxidation part and its reduction part.


Which reaction in the list shown are associated with metabolism?

Reactions such as glycolysis, Krebs cycle, and beta-oxidation are associated with metabolism. These reactions involve the breakdown of nutrients to generate energy for cellular processes and the synthesis of cellular building blocks.


How do you know if an enthalpy change diagram is endothermic or exothermic?

If you plot the reaction coordinate (what I think you mean by "enthalpy change diagram"), the reaction will be exothermic if the products are lower on the graph than the reactants. If they are higher than it is endothermic. For instance, if you go to the linked Wikipedia page (link to the left of this answer), the graph shown is of an exothermic reaction.


What are the potential health effects of carrageenan consumption?

Consuming carrageenan may potentially cause digestive issues, inflammation, and allergic reactions in some individuals. Studies have shown conflicting results on its safety, so it is recommended to consume carrageenan in moderation and be aware of any adverse reactions.


Which of the molecules in this chemical equation shown is a reactanct?

The molecules on the left side of the arrow in a chemical equation are the reactants. They are the starting substances that undergo chemical reactions to form products.


What is heat of reaction and enthalpy of reaction?

Heat of reaction and enthalpy of reaction are the same thing. Enthalpy, or the heat transfer, cannot be measured, however we can measure the CHANGE of enthalpy which is shown by a value of &#8710;H. This measured in kilojoules per mole of reactant. (KJ/mol)This value may be positive or negative. For endothermic reactions (which absorb heat), the &#8710;H value is always positive. For exothermic, where heat is released, the value is negative.


A chemist synthesize tin iodide according to the chemical reactions shown below the chemist starts with 10.0g of tin and excess iodine after the reaction 36.8g of tin iodide are obtained what percent?

69.7