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There was no ozone layer in the very beginning because the process of photosynthesis had to build it up over a long time.

The ozone layer built up starting over 2 billion years ago, and was dense enough (with enough ozone to protect biological organisms from lethal UV light) by about 600 million years ago. Prior to this period, life was restricted to the ocean.

Source: albany.edu/faculty/rgk/atm101/ozone.htm

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