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Depends. It's actually the vapor from gasoline that burns, and it would need a spark of some type to ignite it. If it is in an open container, it will simply evaporate. The vapors of evaporation would be very volatile and are easy to ignite with a spark.

If its in a sealed container, then just being out in the sun should not cause it to ignite. However, that being said, I don't see any benefit to leaving a container of gas out in the sun, so it's probably not a good idea.

presupposing that it is in a container, and that 'in the sun' means in direct sunlight & outdoors. The answer would be no. While gasoline will ignite at a very low temperature (-40 F) with a good spark, it requires a very high temp 475 F or so to self ignite.

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