Threepences were not made from copper.
British 1962 Threepences were made from nickel-brass.
The 1962 Threepences issued by most other British Empire/Commonwealth countries were either partly silver or cupro-nickel, but all with a silver appearance.
Modified coins have no collector value.
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Copper is the normal metal for 1942 copper cents (1943 cents are the ones where the copper ones are worth thousands of dollars) and they are only worth about 3 cents. They are fairly common and not worth all that much.