There is no episode in Bleach where Ichigo and Rukia get married. The two characters share a close bond as friends, but their relationship does not develop into a romantic one in the series.
because bleach is not for romance! so stop that ichiruki ichihime whatever fangirl romance you're on to...
I forgot what number the episode is, but there is one episode when Orihime almost kisses Ichigo, one when Rukia almost tells Ichigo her "feelings" (like she has any...), and when Orihime gets saved by Ichigo. It would more than likely depend on what your version of 'romantic' is, but here's a few: Orihime's confession: Episode 141 Grimmjow vs. Ichigo fight/Orihime cheers on Ichigo: 166 IchiRuki moment? I think its in episode 139. And in the third Bleach movie, "Fade to Black: I Call Your Name", there are too many IchiRuki moments to count, along with a couple RenRuki moments, though there are not any kisses in either the anime or manga to date, so most of this is speculation.
bleach episode 108
As the creator of "Bleach," Tite Kubo has not explicitly stated his personal preference for the Ichigo and Rukia (Ichiruki) pairing. However, his storytelling indicates a deep emotional connection between Ichigo and Rukia, which has fueled the popularity of the Ichiruki ship among fans. Ultimately, how their relationship is interpreted is left to individual fans.
LOL BLEACH IS AT EPISODE 314 now
No clue but will not end up with Rukia Nor orihime. No ichiruki or ichihime says Tite kubo and johnny young bosch
Episode 255
I've included a link to a Bleach Episode Guide at the related link.
it is bleach episode 54 named "day of execution"
Bleach is still ongoing.
You were close Rukia kills her squad captain in bleach episode 49. It is a very sad episode.
Episode 271