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Sound and radio waves are different phenomena. Sound consists of pressure variations in matter, such as air or water. Sound will not travel through a vacuum. Radio waves, like visible light, infrared, ultraviolet, X-rays and gamma rays, are electromagnetic waves that do travel through a vacuum. When you turn on a radio you hear sounds because the transmitter at the radio station has converted the sound waves into electromagnetic waves, which are then encoded onto an electromagnetic wave in the radio frequency range (generally in the range of 500-1600 kHz for AM stations, or 86-107 MHz for FM stations). Radio electromagnetic waves are used because they can travel very large distances through the atmosphere without being greatly attenuated due to scattering or absorption. Your radio receives the radio waves, decodes this information, and uses a speaker to change it back into a sound wave. An animated illustration of this process is given below (mouse-over the images for animations).

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