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At least 12 hours if you've just bought it.

You can use the laptop while it is charging.

I have had laptops connected to their charging device plugged into a wall socket for weeks. Some but not all of them have had problems with their batteries loosing capacity. I suspect the deterioration is due to insufficient "intelligence" in the charger.

First time charging of modern Lithium ion batteries: often at least 12 hours (see the manual).

Subsequent charging cycles: Check the laptops battery status with software (usually installed on a laptop).

Older Nickel Cadmium batteries are a much different story: The NiCd battery should be regularly depleted (and not too slowly either) and recharged fully or a "memory" effect will come into play whereby the battery capacity is drastically reduced.

Sometimes about 3 to 5 hours. Some suggest the best way is to have two batteries used alternately to extend battery life.

Sometimes, there is an indicator that lights up (green) when the battery is at full charge.

12-23 hours is usually a good time frame for the first charge. Make sure you "exercise" the battery by draining and recharging it a few times. Now laptop batteries are almost always Li-ion rechargeable batteries (Li-ion batteries are not susceptible of being over charged if the voltage and current are correct), What's more, most modern laptops have the intelligence to control the charge cycle and stop the charging after the battery has been fully charged.

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12y ago

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