The best video chat system I found would be located here at http://lifehacker.com/5086963/best-video-chat-application there I think that you will find a good video chat.
chat roulette ...
WooMe.com is a very good place to video chat. It depends how old you are. or if you have a facebook chatablanca.com its got a lot of cool extras too!
Gmail video and voice chat are of Good quality. You can try them if you have a good internet connection. Bad connection will lead to it's breakage of network.
omegle does not allow this. For random live chat iddin is also good.
some of the online dating website you can talk and you can video chat!
Skype is a good software for video chatting. You can video chat on Skype for free on your mobile device, laptop or computer.
Omegle is a good one. But if you are looking for good video chat (even tough Omegle has one its a bit glitchy) try Chatroulette! these are both good chat sites! have fun!
You cant schedule to private chat with Miley Cyrus, you have to wait until she comes on mileyworld and goes in a chat room. She hardly goes in the chat rooms so good luck seeing the user name mileycyrus in red in the chat rooms.
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Obviously, you need to subscribe to Skype, and you also need to buy a good quality web camera (webcam). The camera usually fits on top of your computer screen and turns on when you enable video-chat. I enclose a link to the instructions for how to video-chat on Skype.
Free cam chat is good for meeting new people and speaking with new people from all over the world. It is easy to see who your talking too because it is a video chat service.