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Heat is the kinetic energy of particles in motion. Vibrational, rotational, translational energy of particles are different characteristics of heat as we know it.

When uranium or plutonium fission emitting fission fragments, neutrons, etc, then X-ray, gamma, infrared and other light waves are generated which are again absorbed by neighboring particles and a combination of secondary reactions occur that increase the average kinetic energy of particles inside the reactor. Also the hot (high energy) fission fragments and neutrons collide directly with other atoms, making them vibrate faster. This is all heat.

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