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Bitumen or tar is an organic substance that repels water. The stain should therefore first be softened in an organic solvent (petrol or gasoline will do this but this should be done out of doors and away from any flame source) and as much of the bitumen as possible removed. Once this is done a hand cleaning substance (such as 'swarfiga') can be applied and worked in to the stain then the area rinsed in warm water. After this a good wash in a washing machine with normal household detergent should bring the stain out. Alternatively you could take the shirt to a reputable dry cleaners and ask them to remove the stain.

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