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You shouldn't just add flour to the cake mix to stretch it to a third layer, that would upset the delicate balance of flour, protein, acid, leavening agents, and the like. The result wouldn't be good, either from a texture or a taste standpoint. If you want a third layer on your cake, buy an extra box of cake mix and use half of it for the third layer, or buy a bulk cake mix bag from Costco or Smart n' Final, and make the three layers according to the recipe on the bag.

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