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This is actually the heavily over demonstrated"volcano reaction" when vinegar, dilute acetic acid, is mixed with baking soda (sodium bicarbonate.

The bicarbonate ion will be protonated by the acid and carbonic acid will be formed.

The unstable carbonic acid will then dissociate into water and carbon dioxide- lots of great bubbling occurs.

H+ + HCO3- ---> H2CO3 ---> H2O + CO2

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