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Baking soda is sodium hydrogen carbonate (sometimes called sodium bicarbonate) Na HCO3. This is an ionic compound consisting of a sodium cationion and a hydrogen carbonate anion. Its a white crystalline powder.

It works in baking because it decomposes above 700 C

into carbon dioxide, water and sodium carbonate.

2 NaHCO3 → Na2CO3 + H2O + CO2

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